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金屬頂刊雙語導讀丨Scripta Mater. Vol.198, 1 June. 2021

2021-06-03 來源:GS_Metals

 

本期包含金屬材料領域論文7,涵蓋了中錳鋼、高熵合金、增材制造等,國內科研單位包括清華大學、武漢理工大學、天津大學、西安交通大學等(通訊作者單位)

 

Vol. 198 目錄

1. Flash annealing yields a strong and ductile medium Mn steel with heterogeneous microstructure

閃速退火實現異質結構中錳鋼的高強高韌

 

2. Achieving porous tungsten with high porosity by selective dissolution of W-Fe alloy

通過選擇性溶解鎢鐵合金,獲得孔隙率高的多孔鎢

 

3. Formation of abnormal nodular ferrite with interphase precipitation in a vanadium microalloyed low carbon steel

釩微合金化低碳鋼中具有相間析出的異常“結節狀”鐵素體的形成

 

4. The synthesis of TiC dispersed strengthened Mo alloy by freeze-drying technology and subsequent low temperature sintering

采用冷凍干燥和低溫燒結技術制備TiC彌散強化的Mo合金

 

5. Synthesis and characterization of a new TiZrHfNbTaSn high-entropy alloy exhibiting superelastic behavior

具有超彈性的新型TiZrHfNbTaSn高熵合金的合成與表征

 

6. Improving creep resistance of Al-12 wt.% Ce alloy by microalloying with Sc

Sc微合金化提高Al-12 wt.% Ce合金的抗蠕變能力

 

7.Spherical pores as ‘microstructural informants’: Understanding compositional, thermal, and mechanical gyrations in additively manufactured Ti-6Al-4V

球形孔隙作為“微觀組織信息提供者”:了解增材制造Ti-6Al-4V中的成分、熱和機械回旋

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113819

1. Flash annealing yields a strong and ductile medium Mn steel with heterogeneous microstructure

閃速退火實現異質結構中錳鋼的高強高韌

 

Xinhao Wan, Geng Liu, Zhigang Yang, Hao Chen?

Hao Chen: hao.chen@mail.tsinghua.edu.cn  清華大學

https://doi.org/10.1016/j.scriptamat.2021.113819

 

摘要

在中錳鋼(MMS)中,通常利用奧氏體逆轉變工藝(ART)來獲取殘余奧氏體(RA)。本工作中,我們提出了一種閃速退火工藝來處理中錳鋼,該工藝通過奧氏體的“爆發式”形核和C元素的快速配分,在中錳鋼中高效快速地獲取大量的RA。此外,閃速退火還可以構建由再結晶/非再結晶鐵素體晶粒組成的非均質鐵素體基體,從而導致異質變形誘導硬化。和傳統ART工藝處理的MMS,閃速退火工藝處理的MMS中獨特的非均質組織造成了較高的屈服強度和抗拉強度,但塑性幾乎無損失。閃速退火為調控微觀組織和優化力學性能提供了另一種途徑

向上滑動閱覽英文摘要

Austenite reversion treatment (ART) is usually used to obtain retained austenite (RA) in medium Mn steel (MMS). In this contribution, we proposed a flash-annealing strategy to produce MMS, which allows us to efficiently obtain a large amount of RA in MMS via the “explosive” nucleation of austenite and the fast C partitioning. Furthermore, flash-annealing can also render a heterogeneous ferritic matrix consisting of recrystallized/non-recrystallized ferrite grains, leading to heterogeneous deformation-induced hardening. As compared to the conventional ART processed MMS, the unique heterogeneous microstructure in the flash-annealed MMS leads to a higher yield and ultimate tensile strength but a marginal ductility loss. Flash-annealing provides an alternative route to tailor microstructure and optimize the mechanical performance of steels.

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113830

2. Achieving porous tungsten with high porosity by selective dissolution of W-Fe alloy

通過選擇性溶解鎢鐵合金,獲得孔隙率高的多孔鎢

 

Shuai Ge, Jian Zhang?, Zhigang Xu, Guoqiang Luo, Qiang Shen?

Jian Zhang: zhangjian178@whut.edu.cn  武漢理工大學

Qiang Shen: sqqf@263.net  武漢理工大學

https://doi.org/10.1016/j.scriptamat.2021.113830

 

摘要

以鐵為活性元素,通過選擇性溶解,實現了孔隙率高達75.7%的多孔W。結果表明,在800℃下燒結W-Fe偽合金前驅體,納米碳粉有助于原位形成W6Fe6C相,W-WW-Fe界面均由W6Fe6C結合。它能夠使前驅體繼承初始致密物的形態而不變形。Fe選擇性溶解后,W-W連接仍然存在,且形成W骨架。隨著熱處理溫度的升高,孔隙率降低,抗壓強度提高;由于W骨架中W6Fe6C的影響,孔徑變化很小

向上滑動閱覽英文摘要

Porous W with high porosity of 75.7 % was achieved by selective dissolution using Fe as active elements. The results showed that W-Fe pseudo alloy precursor was sintered at 800°C, the nano C powder helped in-situ formation of the W6Fe6C phase and the interface of W-W and W-Fe were both combined by W6Fe6C. It enabled the precursor to inherit the morphology of the green compacts without deformation. W-W connection remained and formed W framework after the selective dissolution of Fe. With the increasing of heat treatment temperature, the porosity decreased and the compressive strength increased, the change of the pore size is very little due to the effect of the W6Fe6C in the W framework.

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113823

3. Formation of abnormal nodular ferrite with interphase precipitation in a vanadium microalloyed low carbon steel

釩微合金化低碳鋼中具有相間析出的異常“結節狀”鐵素體的形成

 

Zhenqiang Wang, Yongjie Zhang?, Goro Miyamoto, Tadashi Furuhara

Yongjie Zhang: yongjie@imr.tohoku.ac.jp

https://doi.org/10.1016/j.scriptamat.2021.113823

 

摘要

在釩微合金化低碳鋼中,觀察到了具有碳化釩相間析出的異常“結節狀”鐵素體。“結節狀”鐵素體的特點是具有高密度的低角度晶界,和周圍奧氏體晶粒的取向與精確的Kurdjumov-Sachs取向關系偏差角度為15-30°。在同一合金中,“結節狀”鐵素體的生長速度明顯快于正常晶界鐵素體。即使在單一的“結節狀”鐵素體中,也確定了碳化釩相間析出多個變體的形成,且每個變體的邊界都是低角度晶界

向上滑動閱覽英文摘要

Abnormal nodular ferrite (NF) with vanadium carbide (VC) interphase precipitation was observed in a vanadium-microalloyed low carbon steel. The NF is characterized as a structure with a high density of low-angle boundaries, having an irrational ferrite/austenite orientation relationship (OR) with angular deviation of 15-30 ° from the exact Kurdjumov-Sachs OR with its neighboring austenite grain into which it grows. The growth of NF is substantially faster than that of normal grain boundary ferrite in the same alloy. Even in one single NF, the formation of multiple variants of VC interphase precipitation was confirmed, each of which was bordered by low-angle boundaries.

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113831

4. The synthesis of TiC dispersed strengthened Mo alloy by freeze-drying technology and subsequent low temperature sintering

采用冷凍干燥和低溫燒結技術制備TiC彌散強化的Mo合金

 

Weiqiang Hu, Zunfeng Du?, Zhizhong Dong, Liming Yu, Tansir Ahamad, Zongqing Ma?

Zunfeng Du: dzf@tju.edu.cn  天津大學

Zongqing Ma: mzq0320@163.com  天津大學

https://doi.org/10.1016/j.scriptamat.2021.113823

 

摘要

采用新型冷凍干燥技術和低溫燒結技術合成了TiC彌散強化的Mo合金。采用冷凍干燥技術引入納米TiC顆粒后,燒結后的Mo-TiC合金具有超細晶粒(2.38 μm)、高密度(99.3%)和高硬度(402±29 HV0.2)。冷凍干燥技術有效地抑制了Mo-TiC合金中第二相顆粒的團聚和生長。此外,我們還提出了凈化和強化理論。缺少CTiC (Ti8C5)會吸附附近的氧雜質,甚至形成TiO2來凈化Mo基體。此外,TiC(002)Ti8C5(0-24)TiO2(111)可以與Mo(110)形成共格界面,增強相界,提高材料強度。穩定的相界面可以釘扎和限制第二相粒子的生長,從而保持其較小的尺寸(<50 nm)

向上滑動閱覽英文摘要

The TiC dispersed strengthened Mo alloys were synthesized by novel freeze-drying technology and subsequent low-temperature sintering. With the introduction of TiC nanoparticles using freeze-drying technology, the sintered Mo-TiC alloys possess ultrafine grain size (2.38 μm), high density (99.3%) and high hardness (402±29 HV0.2). The agglomeration and growth of second phase particles in Mo-TiC alloys were effectively depressed by freeze-drying technology. Moreover, a theory about purification and strengthening is proposed. C-deficient TiC (Ti8C5) will adsorb nearby oxygen impurities and even form TiO2 to purify Mo matrix. Furthermore, TiC (002), Ti8C5 (0-24) and TiO2 (111) can form coherent interfaces with Mo (110) to strengthen their phase boundary and improve material strength. The stable phase interface can pin and limit the growth of these second phase particles, thus maintaining their small size (<50 nm).

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113824

5. Synthesis and characterization of a new TiZrHfNbTaSn high-entropy alloy exhibiting superelastic behavior

具有超彈性的新型TiZrHfNbTaSn高熵合金的合成與表征

 

A. J. Gao, P. Castany, T. Gloriant?

A. Gloriant: Thierry.Gloriant@insa-rennes.fr

https://doi.org/10.1016/j.scriptamat.2021.113824

 

摘要

采用循環拉伸試驗、透射電鏡(TEM)、電子背散射衍射(EBSD)和原位同步X射線衍射(SXRD)等方法研究了一種新型的單相BCC結構Ti35Zr35Hf15Nb5Ta5Sn5高熵合金。該合金在β相和α''相之間發生了可逆的應力誘導馬氏體相變,表現出超彈性行為。拉伸試驗表明存在3.8%的高應變回復,這歸因于<110>β{447}β的再結晶織構

向上滑動閱覽英文摘要

In this study, a new single-phase bcc Ti35Zr35Hf15Nb5Ta5Sn5 high-entropy alloy (HEA) was developed and investigated by means of cyclic tensile tests, transmission electron microscopy (TEM), electron back-scattered diffraction (EBSD) and in situ synchrotron X-ray diffraction (SXRD). The alloy reveals a superelastic behavior due to the reversible stress-induced martensitic transformation that occurs between the β phase and the α'' phase. A high strain recovery of 3.8% is obtained by tensile test, which is attributed to the <110>β{447}β recrystallization texture observed.

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113838

6. Improving creep resistance of Al-12 wt.% Ce alloy by microalloying with Sc

Sc微合金化提高Al-12 wt.% Ce合金的抗蠕變能力

 

Meng Yi, Peng Zhang?, Chong Yang, Pengming Cheng, Shengwu Guo, Gang Liu?, Jun Sun?

Peng Zhang: zhangpeng.mse@xjtu.edu.cn  西安交通大學

Gang Liu: lgsammer@xjtu.edu.cn  西安交通大學

Jun Sun: junsun@xjtu.edu.cn  西安交通大學

https://doi.org/10.1016/j.scriptamat.2021.113838

 

摘要

0.4 wt.% Sc對近共晶Al-12 wt.% Ce合金進行合金化以提高其抗蠕變性能。本文確定了ScCe之間的雙向影響:(i) Ce元素抑制了凝固過程中Sc在液相和固相之間的配分,降低了鑄錠中Sc的顯微偏析;(ii) 時效后Sc原子向Al11Ce3界面遷移,形成Al3Sc薄層或顆粒。前者促進了Al3Sc析出相在Al基體中分布的空間均勻性,后者在Al11Ce3/Alα相界面處引入了額外的晶格錯配應變,抑制了基體位錯攀過Al11Ce3層。這兩種效應都能提高時效Al-12Ce-0.4Sc合金的蠕變抗力,其位錯蠕變具有較高的拉伸應力閾值,在300℃為60 MPa

向上滑動閱覽英文摘要

Strain rate sensitivity and activation volume that dictate the kinetics of plastic deformation along with strain hardening response determine the plastic deformation behaviour of novel high entropy alloys. Although, the deformation behaviour of FCC single-phase Cantor alloy exhibits some similarity to that of conventional FCC solid solutions, the deformation behaviour over a wide range of temperature, strain rate, strain and grain size is unexplored. More importantly, theoretical understanding of solid solution strengthening, stacking fault energy and dislocation activation in 100 percent solute high entropy alloys (HEAs) and their flow kinetics is not yet established. This necessitates development of combined experimental and computational approaches to realise the mechanistic design of new single-phase and multi-phase transformative FCC HEAs to achieve optimum combination of strength and ductility in the novel complex concentrated alloys.

 

 

SCRIPTA

Vol. 198, 1 June. 2021, 113827

 

7. Spherical pores as ‘microstructural informants’: Understanding compositional, thermal, and mechanical gyrations in additively manufactured Ti-6Al-4V

球形孔隙作為“微觀組織信息提供者”:了解增材制造Ti-6Al-4V中的成分、熱和機械回旋

 

Matthew J.Kenney,KatieO'Donnell,Maria J.Quintana,Peter C.Collins?

Peter C.Collins:pcollins@iastate.edu

https://doi.org/10.1016/j.scriptamat.2021.113827

 

摘要

對諸如球形孔隙度等缺陷的詳細分析可以充當信息提供者,提供與增材制造相關的復雜且通常被隱藏的物理特性的一些信息。這些缺陷的存在和性質的變化可以為增材制造過程提供新的見解。本文評估了電子束熔化的Ti-6Al-4V中氣孔周圍的化學成分,晶體學,微觀組織和形貌特征,并將其與不同的掃描策略(光柵和兩點熔化,Dehoff和隨機掃描策略)相關聯。僅在光柵掃描中存在的大球形孔(>25μm)表現出與孔垂直側壁正交的擾動,這可能是由于化學和晶體學變化導致彈性不穩定性的結果,并且是由與循環過程相關的熱應力引起的垂直壓縮,實際上是微屈曲的一種形式。電子背散射衍射圖支持以下理論:這些擾動在高溫下以及最終的固相轉變之前發生

向上滑動閱覽英文摘要

Detailed analysis of defects such as spherical porosity can act as informants, providing some information regarding the complex and often hidden physics associated with additive manufacturing. Variation in the presence and nature of these defects can shed new insights into the AM process. In this paper, the compositional, crystallographic, microstructural, and morphological characteristics surrounding gas pores in Electron Beam Melted Ti-6Al-4V have been assessed and correlated with different scanning strategies (raster and two point melting ones, Dehoff and random). The large spherical pores (>25μm), exclusively present in raster scan, exhibit perturbations normal to the vertical sidewalls of the pores that are likely the result of elastic instabilities resulting from chemical and crystallographic variations and initiated by vertical compression caused by thermal stresses related to the cyclic process – effectively a form of microbuckling. Electron backscatter diffraction maps support the theory that these perturbations occur at elevated temperatures and prior to the final solid-solid phase transformation.